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. 2015 Apr 20;54(17):5228-31.
doi: 10.1002/anie.201500396. Epub 2015 Feb 27.

Copper/palladium synergistic catalysis for the syn- and anti-selective carboboration of alkenes

Kaitlyn M Logan  1 , Kevin B Smith, M Kevin Brown
Affiliations

Copper/palladium synergistic catalysis for the syn- and anti-selective carboboration of alkenes

Kaitlyn M Logan et al. Angew Chem Int Ed Engl. .

Abstract

A method for the diastereoselective carboboration of 1,2-disubstituted styrenes with aryl/vinyl bromides and (Bpin)2 is reported. High diastereoselectivities and yields are observed for the formation of either diastereomer of the product from a single alkene isomer. These reactions provide access to a diverse range of structures from simple starting materials.

Keywords: carboboration; copper; cross-coupling; palladium; synergistic catalysis.

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