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. 2015 Apr 18;51(30):6521-3.
doi: 10.1039/c4cc09212k.

Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

Daniel J Clingerman  1 , William Morris, Joseph E Mondloch, Robert D Kennedy, Amy A Sarjeant, Charlotte Stern, Joseph T Hupp, Omar K Farha, Chad A Mirkin
Affiliations

Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

Daniel J Clingerman et al. Chem Commun (Camb). .

Abstract

The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu3(BCA)2). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m(2) g(-1).

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