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. 2015 Apr 6;54(7):3087-9.
doi: 10.1021/acs.inorgchem.5b00003. Epub 2015 Mar 24.

A dicationic iminophosphane

Ying Kai Loh  1 , Chitra Gurnani  1 , Rakesh Ganguly  1 , Dragoslav Vidović  1
Affiliations

A dicationic iminophosphane

Ying Kai Loh et al. Inorg Chem. .

Abstract

A novel dicationic system containing a PN fragment has been synthesized and structurally characterized. According to the solid-state analysis and theoretical investigation, the dicationic iminophosphane resonance form is the most appropriate description for the dication. However, the contribution from the phosphorus mononitride resonance form is not negligible.

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