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. 2015 May 11;51(38):8058-61.
doi: 10.1039/c5cc01915j. Epub 2015 Apr 13.

Mechanochemical reactions studied by in situ Raman spectroscopy: base catalysis in liquid-assisted grinding

Martina Tireli  1 , Marina Juribašić Kulcsár, Nikola Cindro, Davor Gracin, Nikola Biliškov, Mladen Borovina, Manda Ćurić, Ivan Halasz, Krunoslav Užarević
Affiliations

Mechanochemical reactions studied by in situ Raman spectroscopy: base catalysis in liquid-assisted grinding

Martina Tireli et al. Chem Commun (Camb). .

Abstract

In situ Raman spectroscopy was employed to study the course of a mechanochemical nucleophilic substitution on a carbonyl group. We describe evidence of base catalysis, akin to catalysis in solution, achieved by liquid-assisted grinding.

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