Efficiency Records in Mesoscopic Dye-Sensitized Solar Cells

Abstract

The aim of the present review article is to show the progress achieved in the efficiency of dye-sensitized solar cells (DSSCs) by evolution in the structure and composition of the dye. After an initial brief description of DSSCs and the operating mechanism the major part of the present article is organized according to the type of dye, trying to show the logic in the variation of the dye structure in order to achieve strong binding on the surface of the layer of nanoparticulate TiO2 , efficient interfacial electron injection between the excited dye and the semiconductor, and minimization of the unwanted dark current processes. Besides metal complexes, including polypyridyls and nitrogenated macro rings, organic dyes and inorganic light harvesters such as quantum dots and perovskites have also been included in the review. The last section summarizes the current state of the art and provides an overview on future developments in the field.

Keywords: dyes/pigments • photovoltaic devices • semiconductors • sensitizers • solar cells.