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. 2015 Aug 21;80(16):8390-7.
doi: 10.1021/acs.joc.5b01221. Epub 2015 Aug 4.

Soluble Tetraaminotriptycene Precursors

Nicholas G White  1 , Mark J MacLachlan  1
Affiliations

Soluble Tetraaminotriptycene Precursors

Nicholas G White et al. J Org Chem. .

Abstract

An efficient route to soluble triptycene tetraamines, shape-persistent molecules containing two ortho-phenylenediamine motifs, is reported. These tetraamines are stable, prepared in good yields, easily purified by column chromatography, and can be readily condensed to give a range of imidazole and pyrazine derivatives.

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