Source identification and metallic profiles of size-segregated particulate matters at various sites in Delhi

Abstract

A study of elemental composition in the ambient air of Delhi was carried out in the monsoon, winter and summer seasons at four different sites from August 2012 to April 2013 in the size ranges <1, 1-2.5, 2.5-10 and >10 μm using "Dekati PM10" impactor. At each site, three samples were collected and were analyzed by energy-dispersive X-ray fluorescence (EDXRF). The presence of elements was found to be very common and highly concentrated in aerosol particles at all the sites, which are Na, Al, Si, K, Ca, Zn and Ba. Total suspended particulate matters (TSPMs) of fine particles were found high in comparison to coarse particles at all seasons. The TSPM of fine particles was found to be varied in the range from 303.6 to 416.2 μg/m(3). Similarly, the range of coarse TSPM was observed from 162.9 to 262.8 μg/m(3). Correlation matrices were observed between fine (size ranges <1 and 1-2.5 μm) and coarse (size ranges 2.5-10 and >10 μm) size particles for all elements with seasons. Source apportionments of elements were carried out using MS Excel 2010 through XLSTAT software. The source apportionments between fine and coarse particles were carried out through factor analysis and dominated sources found to be crustal re-suspension and industrial activities.