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. 2015 Oct 25;51(83):15308-11.
doi: 10.1039/c5cc06269a. Epub 2015 Sep 4.

Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO2 removal

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Rational molecular design of PEOlated ladder-structured polysilsesquioxane membranes for high performance CO2 removal

Sunghwan Park et al. Chem Commun (Camb). .

Abstract

Poly(methoxy(polyethyleneoxy)propyl-co-methacryloxypropyl) silsesquioxane membranes with different copolymer ratios were successfully fabricated via UV-induced crosslinking with mechanical stability. By selectively introducing polyethylene oxide (PEO) groups covalently bound to the ladder-structured polysilsesquioxane, we effectively suppressed the PEO crystallization, allowing for excellent CO2/H2 and CO2/N2 separation under single as well as mixed gas conditions.

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