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. 2016 Jan 11;55(2):659-63.
doi: 10.1002/anie.201509233. Epub 2015 Nov 24.

Two-Dimensional Nanoporous Networks Formed by Liquid-to-Solid Transfer of Hydrogen-Bonded Macrocycles Built from DNA Bases

Nerea Bilbao  1 , Iris Destoop  2 , Steven De Feyter  3 , David González-Rodríguez  4
Affiliations

Two-Dimensional Nanoporous Networks Formed by Liquid-to-Solid Transfer of Hydrogen-Bonded Macrocycles Built from DNA Bases

Nerea Bilbao et al. Angew Chem Int Ed Engl. .

Abstract

We present an approach that makes use of DNA base pairing to produce hydrogen-bonded macrocycles whose supramolecular structure can be transferred from solution to a solid substrate. A hierarchical assembly process ultimately leads to two-dimensional nanostructured porous networks that are able to host size-complementary guests.

Keywords: macrocycles; porous networks; self-assembly; supramolecular chemistry; surface assembly.

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