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. 2016 Apr 22;79(4):831-7.
doi: 10.1021/acs.jnatprod.5b00914. Epub 2016 Feb 25.

Iodine, a Mild Reagent for the Aromatization of Terpenoids

Victoriano Domingo  1 , Consuelo Prieto  1 , Lucia Silva  2 , Jesús M L Rodilla  2 , José F Quílez del Moral  1 , Alejandro F Barrero  1
Affiliations

Iodine, a Mild Reagent for the Aromatization of Terpenoids

Victoriano Domingo et al. J Nat Prod. .

Abstract

Efficient procedures based on the use of iodine for the aromatization of a series of terpenoids possessing diene and homoallylic or allylic alcohol functionalities are described. Different examples are reported as a proof-of-concept study. Furthermore, iodine also proved to mediate the dehydrogenation of testosterone.

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