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. 2016 Jul 12;52(58):9105-8.
doi: 10.1039/c6cc00575f.

Cyclopentadiene-mediated hydride transfer from rhodium complexes

C L Pitman  1 , O N L Finster  1 , A J M Miller  1
Affiliations

Cyclopentadiene-mediated hydride transfer from rhodium complexes

C L Pitman et al. Chem Commun (Camb). .

Abstract

Attempts to generate a proposed rhodium hydride catalytic intermediate instead resulted in isolation of (Cp*H)Rh(bpy)Cl (1), a pentamethylcyclopentadiene complex, formed by C-H bond-forming reductive elimination from the fleeting rhodium hydride. The hydride transfer ability of diene 1 was explored through thermochemistry and hydride transfer reactions, including the reduction of NAD(+).

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