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. 2016 Mar 30;138(12):4010-3.
doi: 10.1021/jacs.6b01591. Epub 2016 Mar 17.

Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C-H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes

Miyuki Hatano  1 , Yusuke Ebe  1 , Takahiro Nishimura  1 , Hideki Yorimitsu  1
Affiliations

Asymmetric Alkylation of N-Sulfonylbenzamides with Vinyl Ethers via C-H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes

Miyuki Hatano et al. J Am Chem Soc. .

Abstract

Asymmetric alkylation of N-sulfonylbenzamides with vinyl ethers via a directed C-H bond activation gave high yields of the corresponding addition products with high branch- and enantioselectivity.

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