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. 2016 Apr;16(2):835-56.
doi: 10.1002/tcr.201500280. Epub 2016 Mar 10.

Transition Metal-Catalyzed Carbonylative C-H Bond Functionalization of Arenes and C(sp(3))-H Bond of Alkanes

Sandip T Gadge  1 , Prashant Gautam  1 , Bhalchandra M Bhanage  1
Affiliations

Transition Metal-Catalyzed Carbonylative C-H Bond Functionalization of Arenes and C(sp(3))-H Bond of Alkanes

Sandip T Gadge et al. Chem Rec. 2016 Apr.

Abstract

In this article, we present the progress made in the area of carbonylative C-H functionalization, with special emphasis on arenes and alkanes. The importance of directing group assistance and C-H functionalization using CO surrogates is also included. The budding development in the area of transition metal-catalyzed C(sp(3))-H activation makes us feel it necessary to file a summary on the past, as well as current, contributions and a prospective outlook on the transition metal-catalyzed carbonylative transformation of C-H bonds, which is the focus of this review.

Keywords: CH activation; alkanes; arenes; carbonylation; transition metals.

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