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. 2016 May 19;52(43):7020-3.
doi: 10.1039/c6cc01813k.

bcTol : a highly water-soluble biradical for efficient dynamic nuclear polarization of biomolecules

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bcTol : a highly water-soluble biradical for efficient dynamic nuclear polarization of biomolecules

Anil P Jagtap et al. Chem Commun (Camb). .

Abstract

Dynamic nuclear polarization (DNP) is an efficient method to overcome the inherent low sensitivity of magic-angle spinning (MAS) solid-state NMR. We report a new polarizing agent (), designed for biological applications, that yielded an enhancement value of 244 in a microcrystalline SH3 domain sample at 110 K.

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