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. 2016 Jun 3;18(11):2758-61.
doi: 10.1021/acs.orglett.6b01250. Epub 2016 May 23.

Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C-S Bond Cleavage

Yuta Uetake  1 , Takashi Niwa  1 , Takamitsu Hosoya  1   2
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Rhodium-Catalyzed ipso-Borylation of Alkylthioarenes via C-S Bond Cleavage

Yuta Uetake et al. Org Lett. .

Abstract

Rhodium-catalyzed transformation of alkyl aryl sulfides into arylboronic acid pinacol esters via C-S bond cleavage is reported. In combination with transition-metal-catalyzed sulfanyl group-guided regioselective C-H borylation reactions of alkylthioarenes, this method allows the synthesis of a diverse range of multisubstituted arenes.

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