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. 2016 Aug 19;81(16):7148-54.
doi: 10.1021/acs.joc.6b01002. Epub 2016 Jul 20.

1,2-Alkylarylation of Styrenes with α-Carbonyl Alkyl Bromides and Indoles Using Visible-Light Catalysis

Meng Li  1 , Ji Yang  1 , Xuan-Hui Ouyang  1 , Yuan Yang  1 , Ming Hu  1 , Ren-Jie Song  2 , Jin-Heng Li  1   2
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1,2-Alkylarylation of Styrenes with α-Carbonyl Alkyl Bromides and Indoles Using Visible-Light Catalysis

Meng Li et al. J Org Chem. .

Abstract

A new intermolecular 1,2-alkylarylation of styrenes with α-carbonyl alkyl bromides and indoles using fac-[Ir(ppy)3] as the photoredox catalyst has been developed. The method allows the simultaneous formation of two new carbon-carbon bonds through three component reaction, and represents a new single-electron transfer (SET) strategy for the 1,2-alkylarylation of the styrenes with broad substrate scope and excellent functional group tolerance.

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