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. 2016 Aug 21;14(31):7579-84.
doi: 10.1039/c6ob01299j. Epub 2016 Jul 22.

Nickel catalyzed α-arylation of ketones with aryltrimethylammonium triflates

Jing Li  1 , Zhong-Xia Wang
Affiliations

Nickel catalyzed α-arylation of ketones with aryltrimethylammonium triflates

Jing Li et al. Org Biomol Chem. .

Abstract

Nickel-catalyzed α-arylation of ketones involving aromatic C-N cleavage has been accomplished. Intermolecular coupling of aromatic ketones with a variety of aryltrimethylammonium triflates was achieved in the presence of Ni(COD)2, IPr·HCl, and LiOBu(t), giving α-arylated ketones in reasonable to excellent yields.

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