Synthesis of esters via sp(3) C-H functionalisation
- PMID: 27488288
- DOI: 10.1039/c6ob01250g
Synthesis of esters via sp(3) C-H functionalisation
Abstract
Oxidative C-O bond formation via sp(3) C-H functionalisation represents an attractive approach for the synthesis of esters. This review focuses on the recent advances of sp(3) C-H bond functionalisation strategies for ester synthesis from unconventional precursors using transition metal/metal free catalysts in combination with various oxidants. Various classes of esters and the mechanisms of their formation are discussed with numerous examples.
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