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. 2016 Aug 18;52(69):10533-6.
doi: 10.1039/c6cc04835h.

Cobalt-catalyzed C-H olefination of aromatics with unactivated alkenes

Ramasamy Manoharan  1 , Ganesan Sivakumar  1 , Masilamani Jeganmohan  1
Affiliations

Cobalt-catalyzed C-H olefination of aromatics with unactivated alkenes

Ramasamy Manoharan et al. Chem Commun (Camb). .

Abstract

A cobalt-catalyzed C-H olefination of aromatic and heteroaromatic amides with unactivated alkenes, allyl acetates and allyl alcohols is described. This method offers an efficient route for the synthesis of vinyl and allyl benzamides in a highly stereoselective manner. It is observed that the ortho substituent on the benzamide moiety is crucial for the observation of allylated products in unactivated alkenes.

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