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. 2016 Sep 6;55(17):8263-6.
doi: 10.1021/acs.inorgchem.6b01504. Epub 2016 Aug 12.

Room-Temperature Characterization of a Mixed-Valent μ-Hydroxodicopper(II,III) Complex

James A Isaac  1 , Federica Gennarini  2 , Isidoro López  2 , Aurore Thibon-Pourret  1   3 , Rolf David  1 , Gisèle Gellon  1 , Béatrice Gennaro  1 , Christian Philouze  1 , Franc Meyer  4 , Serhiy Demeshko  4 , Yves Le Mest  2 , Marius Réglier  5 , Hélène Jamet  1 , Nicolas Le Poul  2 , Catherine Belle  1
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Room-Temperature Characterization of a Mixed-Valent μ-Hydroxodicopper(II,III) Complex

James A Isaac et al. Inorg Chem. .

Abstract

Bis(μ-hydroxo)dicopper(II,II) bearing a naphthyridine-based ligand has been synthesized and characterized in the solid state and solution. Cyclic voltammetry at room temperature displays a reversible redox system that corresponds to the monoelectronic oxidation of the complex. Spectroscopic and time-resolved spectroelectrochemical data coupled to theoretical results support the formation of a charge-localized mixed-valent Cu(II,III)2 species.

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