doi: 10.1002/anie.201606244.
Epub 2016 Aug 17.
New Avenues in s-Block Chemistry: Beryllium(0) Complexes
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- PMID: 27530611
- DOI: 10.1002/anie.201606244
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New Avenues in s-Block Chemistry: Beryllium(0) Complexes
Angew Chem Int Ed Engl.
.
Free article
Abstract
A rarely used element: The chemistry of ligand-stabilized complexes in oxidation state zero was recently extended to the s block with the discovery of a Be1 complex stabilized by a cyclic (alkyl)(amino)carbene. Combined experimental and theoretical studies provided conclusive evidence that the complex contains beryllium(0).
Keywords: beryllium; carbenes; low-valent compounds; main-group elements.
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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