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. 2016 Oct 5;138(39):12779-12782.
doi: 10.1021/jacs.6b08507. Epub 2016 Sep 21.

Branch-Selective Hydroarylation: Iodoarene-Olefin Cross-Coupling

Samantha A Green  1 , Jeishla L M Matos  1 , Akiko Yagi  1 , Ryan A Shenvi  1
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Free article

Branch-Selective Hydroarylation: Iodoarene-Olefin Cross-Coupling

Samantha A Green et al. J Am Chem Soc. .
Free article

Abstract

A combination of cobalt and nickel catalytic cycles enables a highly branch-selective (Markovnikov) olefin hydroarylation. Radical cyclization and ring scission experiments are consistent with hydrogen atom transfer (HAT) generation of a carbon-centered radical that leads to engagement of a nickel cycle.

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