Stability of metal-organic frameworks under gamma irradiation
- PMID: 27722563
- DOI: 10.1039/c6cc06878b
Stability of metal-organic frameworks under gamma irradiation
Abstract
We report the study of the resistance of archetypal MOFs (MILs, HKUST-1, UiO-66, and ZIF-8) under gamma irradiation. The different porous solids were irradiated with doses up to 1.75 MGy. All the MOFs constructed with transition metals (Cu2+, Zn2+, Zr4+) exhibit an evident destruction of the framework, whereas the compounds constructed with aluminium remain intact.
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