Synergistically strengthened 3D micro-scavenger cage adsorbent for selective removal of radioactive cesium
- PMID: 27917913
- PMCID: PMC5137142
- DOI: 10.1038/srep38384
Synergistically strengthened 3D micro-scavenger cage adsorbent for selective removal of radioactive cesium
Abstract
A novel microporous three-dimensional pomegranate-like micro-scavenger cage (P-MSC) composite has been synthesized by immobilization of iron phyllosilicates clay onto a Prussian blue (PB)/alginate matrix and tested for the removal of radioactive cesium from aqueous solution. Experimental results show that the adsorption capacity increases with increasing the inactive cesium concentration from 1 ppm to 30 ppm, which may be attributed to greater number of adsorption sites and further increase in the inactive cesium concentration has no effect. The P-MSC composite exhibit maximum adsorption capacity of 108.06 mg of inactive cesium per gram of adsorbent. The adsorption isotherm is better fitted to the Freundlich model than the Langmuir model. In addition, kinetics studies show that the adsorption process is consistent with a pseudo second-order model. Furthermore, at equilibrium, the composite has an outstanding adsorption capacity of 99.24% for the radioactive cesium from aqueous solution. This may be ascribed to the fact that the AIP clay played a substantial role in protecting PB release from the P-MSC composite by cross-linking with alginate to improve the mechanical stability. Excellent adsorption capacity, easy separation, and good selectivity make the adsorbent suitable for the removal of radioactive cesium from seawater around nuclear plants and/or after nuclear accidents.
Figures






References
-
- Buesseler K., Aoyama M. & Fukasawa M. Impacts of the Fukushima nuclear power plants on marine radioactivity. Environ. Sci. Technol. 45, 9931–9935 (2011). - PubMed
-
- Brumfiel G. Fukushima set for epic clean-up. Nature 472, 146–147 (2011). - PubMed
-
- Bandazhevsky Y. I. Radioactive cesium and the heart: pathophysiological aspects. The Belrad Institute, 1–59 (2001).
-
- Vipin A. K., Hu B. & Fugetsu B. Prussian blue caged in alginate/calcium beads as adsorbents for removal of cesium ions from contaminated water. J. Hazard. Mater. 258, 93–101 (2013). - PubMed
Publication types
LinkOut - more resources
Full Text Sources
Other Literature Sources
Miscellaneous