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. 2017 Feb 2;53(11):1817-1820.
doi: 10.1039/c6cc09457k.

Desymmetrization of aziridine with malononitrile using cinchona alkaloid amide/zinc(ii) catalysts

Noriyuki Shiomi  1 , Mami Kuroda  2 , Shuichi Nakamura  1
Affiliations

Desymmetrization of aziridine with malononitrile using cinchona alkaloid amide/zinc(ii) catalysts

Noriyuki Shiomi et al. Chem Commun (Camb). .

Abstract

The catalytic enantioselective desymmetrization of aziridines with malononitrile has been developed. Good yield and enantioselectivity were obtained by using cinchona alkaloid amide/Zn(ii) catalysts. The obtained product can be converted to β-aminoester, β-aminoamide and triamide compounds.

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