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. 2017 Mar 13;56(12):3187-3190.
doi: 10.1002/anie.201611720. Epub 2017 Feb 10.

Ni-Catalyzed Stannylation of Aryl Esters via C-O Bond Cleavage

Yiting Gu  1 , Rúben Martín  1   2
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Ni-Catalyzed Stannylation of Aryl Esters via C-O Bond Cleavage

Yiting Gu et al. Angew Chem Int Ed Engl. .

Abstract

A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents via Csp2 -O cleavage is described. This protocol is characterized by its wide scope, including challenging combinations, thus enabling access to versatile building blocks and orthogonal C-heteroatom bond formations.

Keywords: C−O cleavage; aryl esters; cross-coupling; nickel.

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