Efficiency estimates and practical aspects of an optical Kerr gate for time-resolved luminescence spectroscopy

Abstract

We report experience of assembling an optical Kerr gate setup at the Femtosecond Laser Center for collective use at the Institute of Physics of the National Academy of Sciences of Ukraine. This offers an inexpensive solution to the problem of time-resolved luminescence spectroscopy. Practical aspects of its design and alignment are discussed and its main characteristics are evaluated. Theoretical analysis and numerical estimates are performed to evaluate the efficiency and the response time of an optical Kerr gate setup for fluorescence spectroscopy with subpicosecond time resolution. The theoretically calculated efficiency is compared with the experimentally measured one of ~12% for Crown 5 glass and ~2% for fused silica. Other characteristics of the Kerr gate are analyzed and ways to improve them are discussed. A method of compensation for the refractive index dispersion in a Kerr gate medium is suggested. Examples of the application of the optical Kerr gate setup for measurements of the time-resolved luminescence of Astra Phloxine and Coumarin 30 dyes and both linear and nonlinear chirp parameters of a supercontinuum are presented.