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Review
. 2017 May 15;56(21):5668-5675.
doi: 10.1002/anie.201612516. Epub 2017 Mar 22.

Exploiting Octahedral Stereocenters: From Enzyme Inhibition to Asymmetric Photoredox Catalysis

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Review

Exploiting Octahedral Stereocenters: From Enzyme Inhibition to Asymmetric Photoredox Catalysis

Eric Meggers. Angew Chem Int Ed Engl. .

Abstract

A simple concept, namely exploiting the structural and stereochemical complexity of octahedral metal complexes, can have unexpected impact in different areas of chemical research, from medicinal chemistry and chemical biology to asymmetric catalysis and photoredox chemistry.

Keywords: asymmetric catalysis; coordination geometry; enzyme inhibition; octahedral metal complexes; photoredox chemistry.

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