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. 2017 Apr 27;53(35):4779-4782.
doi: 10.1039/c7cc01058c.

Phase-transfer catalyzed asymmetric synthesis of α,β-unsaturated γ,γ-disubstituted γ-lactams

Alexander Arlt  1 , Hideaki Toyama, Koji Takada, Takuya Hashimoto, Keiji Maruoka
Affiliations

Phase-transfer catalyzed asymmetric synthesis of α,β-unsaturated γ,γ-disubstituted γ-lactams

Alexander Arlt et al. Chem Commun (Camb). .

Abstract

The direct enantioselective vinylogous Michael addition of unsaturated γ-monosubstituted γ-lactams was realized by using chiral phase-transfer catalysis as a means to give enantioenriched γ,γ-disubstituted γ-lactams.

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