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. 2017 Jun 27;53(52):7088-7091.
doi: 10.1039/c7cc02427d.

Novel chemical probes for the investigation of nonribosomal peptide assembly

Y T Candace Ho  1 , Daniel J Leng  1 , Francesca Ghiringhelli  2 , Ina Wilkening  1 , Dexter P Bushell  1 , Otto Kostner  3 , Elena Riva  1 , Judith Havemann  1 , Daniele Passarella  4 , Manuela Tosin  1
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Free article

Novel chemical probes for the investigation of nonribosomal peptide assembly

Y T Candace Ho et al. Chem Commun (Camb). .
Free article

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Abstract

Chemical probes were devised and evaluated for the capture of biosynthetic intermediates involved in the bio-assembly of the nonribosomal peptide echinomycin. Putative intermediate peptide species were isolated and characterised, providing fresh insights into pathway substrate flexibility and paving the way for novel chemoenzymatic approaches towards unnatural peptides.

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