Advances and challenges in the rheology of concentrated emulsions and nanoemulsions

Abstract

We review advances that have been made in the rheology of concentrated emulsions and nanoemulsions, which can serve as model soft materials that have highly tunable viscoelastic properties at droplet volume fractions near and above the glass transition and jamming point. As revealed by experiments, simulations, and theoretical models, interfacial and positional structures of droplets can depend on the applied flow history and osmotic pressure that an emulsion has experienced, thereby influencing its key rheological properties such as viscoelastic moduli, yield stress and strain, and flow behavior. We emphasize studies of monodisperse droplets, since these have led to breakthroughs in the fundamental understanding of dispersed soft matter. This review also covers the rheological properties of attractive emulsions, which can exhibit a dominant elasticity even at droplet volume fractions far below maximal random jamming of hard spheres.