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. 2017 Sep 12;53(73):10180-10183.
doi: 10.1039/c7cc06106d.

Nickel-catalyzed methylation of aryl halides/tosylates with methyl tosylate

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Nickel-catalyzed methylation of aryl halides/tosylates with methyl tosylate

Jiawang Wang et al. Chem Commun (Camb). .

Abstract

This work describes the cross-electrophile methylation of aryl bromides and aryl tosylates with methyl tosylate. The mild reaction conditions allow effective methylation of a wide set of heteroaryl electrophiles and dimethylation of dibromoarenes.

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