Photocatalytic removal of Congo red dye using MCM-48/Ni2O3 composite synthesized based on silica gel extracted from rice husk ash; fabrication and application

Abstract

MCM-48 mesoporous silica was successfully synthesized from silica gel extracted from rice husk ash and loaded by nickel oxide (Ni₂O₃). The resulted composite was characterized using X-ray diffraction, scanning electron microscope, and UV-vis spectrophotometer. The role of MCM-48 as catalyst support in enhancing the photocatalytic properties of nickel oxide was evaluated through the photocatalytic degradation of Congo red dye under visible light source. MCM-48 as catalyst support for Ni₂O₃ shows considerable enhancement in the adsorption capacity by 17% and 29% higher than the adsorption capacity of MCM-48 and Ni₂O₃, respectively. Additionally, the photocatalytic degradation percentage increased by about 64% relative to the degradation percentage using Ni₂O₃ as a single component. The adsorption mechanism of MCM-48/Ni₂O₃ is chemisorption process of multilayer form. The using of MCM-48 as catalyst support for Ni₂O₃ enhanced the adsorption capacity and the photocatalytic degradation through increasing the surface area and prevents the nickel oxide particles from agglomeration. This was done through fixing nickel oxide particles throughout the porous structure which providing more exposed active adsorption sites and active photocatalyst sites for the incident photons. Based on the obtained results, supporting of nickel oxide particles onto MCM-48 are promising active centers for the degradation of Congo red dye molecules.

Keywords: Catalyst support; Congo red dye; MCM-48; Ni(2)O(3); Photocatalyst; Rice husk ash.