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. 2017 Oct 6;19(19):5272-5275.
doi: 10.1021/acs.orglett.7b02543. Epub 2017 Sep 14.

N-Heterocyclic Carbene Catalyzed Stereoselective Glycosylation of 2-Nitrogalactals

Jia-Lin Liu  1 , Yu-Tong Zhang  1 , Hang-Fan Liu  1 , Ling Zhou  1 , Jie Chen  1
Affiliations

N-Heterocyclic Carbene Catalyzed Stereoselective Glycosylation of 2-Nitrogalactals

Jia-Lin Liu et al. Org Lett. .

Abstract

An efficient N-heterocyclic carbene catalyzed glycosylation of 2-nitrogalactals with alcohols and phenol has been developed for the first time. A wide variety of 1,2-cis-2-nitroglycosides can be obtained with good to excellent yields and high to excellent α-selectivities.

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