Polycyclic aromatic hydrocarbons and organochlorine pesticides in surface water from the Yongding River basin, China: Seasonal distribution, source apportionment, and potential risk assessment

Abstract

The presence of 17 polycyclic aromatic hydrocarbons (PAHs) and 15 persistent organochlorine pesticides (OCPs) in surface water of the Yongding River Basin was analyzed through GC/MS/MS during the spring and summer at 46 sampling sites. The goal was to investigate their seasonal distribution, possible sources, and potential risk. Our results showed that the total PAH concentration in surface water of Yongding River Basin ranged from 41.60 to 1482.60ng/L with a mean value of 137.85ng/L in the spring, and from 53.53 to 506.53ng/L with a mean value of 124.43ng/L in the summer. The total OCP concentration ranged from <0.08 to 197.71ng/L with a mean value of 7.69ng/L in the spring, and from <0.08 to 93.58ng/L with a mean value of 7.92ng/L in the summer. Moreover, the total PAH concentration was slightly lower in the spring than in the summer, whereas the total OCP concentration was similar between seasons. Source analysis indicated that combustion sources and petroleum sources both contributed to the presence of PAHs. Historical environmental residues and long range atmospheric transport were the major sources of HCH and DDT contamination. The concentrations of total PAHs and single PAHs including benz(a)anthracene, benzo(a)pyrene, benz(b)fluoranthene, and benz(k)fluoranthene in surface water at some sampling sites exceeded the water environmental quality standards of China and several other countries or organizations. This indicated a potential threat to human health from the consumption of aquatic organisms due to PAH bioaccumulation. The concentrations of α-HCH, p,p'-DDE, and p,p'-DDD at several sampling sites exceeded the limit for human health specified in the ambient water quality criteria developed by the US Environmental Protection Agency, which indicated that these pollutants provide potential hazards to the residents around the sampling sites.

Keywords: Distribution; Organochlorine pesticides; Polycyclic aromatic hydrocarbons; Risk assessment; Source apportionment; Yongding River basin.