doi: 10.1021/jacs.7b11416.
Epub 2017 Dec 4.
Iron-Catalyzed 1,2-Selective Hydroboration of N-Heteroarenes
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- PMID: 29192777
- DOI: 10.1021/jacs.7b11416
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Iron-Catalyzed 1,2-Selective Hydroboration of N-Heteroarenes
J Am Chem Soc.
.
Abstract
A N2-bridged diiron complex [Cp*(Ph2PC6H4S)Fe]2(μ-N2) (1) has been found to catalyze the hydroboration of N-heteroarenes with pinacolborane, giving N-borylated 1,2-reduced products with high regioselectivity. The catalysis is initiated by coordination of N-heteroarenes to the iron center, while the B-H bond cleavage is the rate-determining step.
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