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. 2018 Feb 13;54(14):1698-1701.
doi: 10.1039/c7cc07724f.

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

Kang Zhang  1 , Yunjun Shen, Jiyong Liu, Bernhard Spingler, Simon Duttwyler
Affiliations

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks

Kang Zhang et al. Chem Commun (Camb). .

Abstract

The crystal structure of the deprotonated monocarba-closo-dodecaborate [12-CN-CB11H11]- is reported. This dianion, featuring a delocalized endohedral negative charge and an exo-cluster C-[Li] moiety, was used for the synthesis of ditopic ligands with the potential to form novel supramolecular frameworks.

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