Effect of nanostructured zirconium dioxide incorporation in an experimental adhesive resin

Abstract

Objectives: The aim of this study was to evaluate the influence of nanostructured zirconium dioxide incorporation in an experimental adhesive resin.

Methods: ZrO₂ particles were characterized by X-ray diffraction (XRD), micro-Raman spectroscopy and Brunauer-Emmett-Teller (B.E.T). Experimental adhesive resins were formulated with 0, 0.5, 1, 4.8, and 9.1% ZrO₂ in weight. The adhesives were evaluated based on degree of conversion (DC), radiopacity, softening in solvent and microtensile bond strength (μTBS) 24 h and after 1 year of aging. Mineral deposition at the hybrid layer was assessed with micro-Raman spectroscopy at the baseline and after 14 days.

Results: XRD showed monoclinic and tetragonal phases of ZrO_2.particles. B.E.T data revealed a surface area of 37.41 m²/g, and typical chemical groups were shown on the Raman spectra_. The addition of ZrO₂ did not influence the radiopacity. The addition of 4.8% and 9.1 wt.% ZrO₂ showed higher initial hardness with increased softening in solvent (P < 0.05) and promoted mineral deposition at the dentin interface. DC was significantly increased in the group with 1% ZrO₂ (P < 0.05). The μTBS test showed difference on the group with 9.1 wt.% of ZrO₂, with a significant reduction after aging.

Conclusion: The incorporation of ZrO₂ promoted mineral deposition on the adhesive interface and the addition of 1 wt.% caused a significant increase on the DC without compromising the other physicochemical characteristics, which may prove promising for the development of new dental adhesive systems.

Clinical relevance: The mineral deposition on the hybrid layer can result in a longer stability of the adhesive, thus delaying the hydrolytic degradation.

Keywords: Dentin bonding agents; Nanostructures; Zirconium dioxide.