Sorption and mobility of 14C-fenamiphos in Brazilian soils

Abstract

Although fenamiphos is widely used as an insecticide and nematicide in bowling greens and agriculture, information on its sorption in tropical soils is limited. In this study, mobility, sorption, and desorption dynamics of ¹⁴C-fenamiphos in three contrasting Brazilian soils were examined both in batch and column experiments. Fenamiphos sorption coefficients (K _d ) were 2.33, 3.86, and 3.9 L kg^-1 for the three soils tested. The insecticide exhibited linear adsorption isotherms in all the three soils, and desorption was in a range of 30-40% during a 72-h period. With its low mobility, fenamiphos did not percolate through the soil profile even after 48 h. However, there is a risk of leaching to water bodies due to runoff because of its high solubility in water. In view of the fact that fenamiphos and its oxidation products are highly toxic to aquatic invertebrates and could affect the soil microbial activities even at low concentrations, the present information is of great importance in risk assessment of fenamiphos in the environment.

Keywords: Desorption; Fenamiphos; Mobility; Sorption; Tropical soils.