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. 2018 Feb 28;16(9):1448-1451.
doi: 10.1039/c8ob00023a.

B(C6F5)3-catalyzed transfer hydrogenations of imines with Hantzsch esters

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B(C6F5)3-catalyzed transfer hydrogenations of imines with Hantzsch esters

Qiaotian Wang et al. Org Biomol Chem. .

Abstract

Highly efficient transfer hydrogenations of imines were realized with as low as 0.1 mol% of B(C6F5)3 by using Hantzsch esters as a hydrogen source, furnishing a variety of amines in 80-99% yields. For the asymmetric transfer hydrogenations, up to 38% ee was obtained with chiral diene-derived boron Lewis acids.

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