Synthesis of hierarchical Co3O4@NiO core-shell nanotubes with a synergistic catalytic activity for peroxidase mimicking and colorimetric detection of dopamine

Abstract

Fabrication of core-shell nanostructured catalyst is a promising way for tuning its catalytic performance due to the highly active interface and rich redox properties. In this work, hierarchical Co₃O₄@NiO core-shell nanotubes are fabricated by the deposition of NiO shells via a chemical bath treatment using electrospun Co-C composite nanofibers as templates, followed by a calcination process in air. The as-prepared Co₃O₄@NiO core-shell nanotubes exhibit a uniform and novel hollow structure with Co₃O₄ nanoparticles attached to the inner wall of NiO nanotubes and excellent catalytic activity toward the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) in the presence of H₂O₂. Due to the synergistic effect, the peroxidase-like activity of the Co₃O₄@NiO core-shell nanotubes is much higher than that of individual Co₃O₄ and NiO components. Owing to the superior peroxidase-like activity, a simple and rapid colorimetric approach for the detection of dopamine with a detection limit of 1.21µM and excellent selectivity has been developed. It is anticipated that the prepared Co₃O₄@NiO core-shell nanotubes are promising materials applied for biomedical analysis and environmental monitoring.

Keywords: Co(3)O(4)@NiO core-shell nanotubes; Colorimetric detection; Dopamine; Electrospinning; Peroxidase mimic.