Double-layer force suppression between charged microspheres

Abstract

In this paper we propose a protocol to suppress double-layer forces between two microspheres immersed in a dielectric medium, being one microsphere metallic at a controlled potential ψ_{M} and the other a charged one either metallic or dielectric. The approach is valid for a wide range of distances between them. We show that, for a given distance between the two microspheres, the double-layer force can be totally suppressed by simply tuning ψ_{M} up to values dictated by the linearized Poisson-Boltzmann equation. Our key finding is that such values can be substantially different from the ones predicted by the commonly used proximity force approximation, also known as the Derjaguin approximation, even in situations where the latter is expected to be accurate. The proposed procedure can be used to suppress the double-layer interaction in force spectroscopy experiments, thus paving the way for measurements of other surface interactions, such as Casimir dispersion forces.