Water Splitting on Rutile TiO2 -Based Photocatalysts

Abstract

Water splitting using a semiconductor photocatalyst with sunlight has long been viewed as a potential means of large-scale H₂ production from renewable resources. Different from anatase TiO₂ , rutile enables preferential water oxidation, which is useful for the construction of a Z-scheme water-splitting system. The combination of rutile TiO₂ with a suitable H₂ -evolution photocatalyst such as a Pt-loaded BaZrO₃ -BaTaO₂ N solid solution enables solar-driven water splitting into H₂ and O₂ . While rutile TiO₂ is a wide-gap semiconductor with a bandgap of 3.0 eV, co-doping of rutile TiO₂ with certain metal ions and/or nitrogen produces visible-light-driven photocatalysts, which are also useful as a component for water oxidation in visible-light-driven Z-scheme water splitting. The key to achieving highly efficient water oxidation is to maintain a charge balance of dopants in the rutile, because single doping typically produces trap states that capture photogenerated electrons and/or holes. Here we provide a concise summary of rutile TiO₂ -based photocatalysts for water-splitting systems.

Keywords: artificial photosynthesis; heterogeneous photocatalysis; mixed-anion compounds; semiconductors; solar fuels.