Exploratory Study of Zn xPbO y Photoelectrodes for Unassisted Overall Solar Water Splitting

Abstract

A complete photoelectrochemical (PEC) water splitting system requires a photocathode and a photoanode to host water oxidation and reduction reactions, respectively. It is thus important to search for efficient photoelectrodes capable of full water splitting. Herein, we report on an exploratory study of a new photoelectrode family of Zn _xPbO _y-ZnPbO₃ and Zn₂PbO₄-similarly synthesized by a simple and economical method and shown to be a promising photocathode (p-type semiconductor) and photoanode (n-type semiconductor), respectively. From PEC measurements, the bare ZnPbO₃ photocathode achieved a photocurrent density of -0.94 mA/cm² at 0 V versus reversible hydrogen electrode (RHE), whereas the pristine Zn₂PbO₄ photoanode delivered a photocurrent density of 0.51 mA/cm² at 1.23 V versus RHE. By depositing suitable cocatalysts onto the photoelectrodes established above, we also demonstrated unassisted overall PEC water splitting, a rare case, if any, wherein a single material system is compositionally engineered for either of the photoelectrodes.

Keywords: ZnxPbOy photoelectrodes; cocatalyst; photoelectrochemical; solar water splitting; unassisted overall.