Lead-Free Perovskite Nanowire-Employed Piezopolymer for Highly Efficient Flexible Nanocomposite Energy Harvester

Abstract

In the past two decades, mechanical energy harvesting technologies have been developed in various ways to support or power small-scale electronics. Nevertheless, the strategy for enhancing current and charge performance of flexible piezoelectric energy harvesters using a simple and cost-effective process is still a challenging issue. Herein, a 1D-3D (1-3) fully piezoelectric nanocomposite is developed using perovskite BaTiO₃ (BT) nanowire (NW)-employed poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) for a high-performance hybrid nanocomposite generator (hNCG) device. The harvested output of the flexible hNCG reaches up to ≈14 V and ≈4 µA, which is higher than the current levels of even previous piezoceramic film-based flexible energy harvesters. Finite element analysis method simulations study that the outstanding performance of hNCG devices attributes to not only the piezoelectric synergy of well-controlled BT NWs and within P(VDF-TrFE) matrix, but also the effective stress transferability of piezopolymer. As a proof of concept, the flexible hNCG is directly attached to a hand to scavenge energy using a human motion in various biomechanical frequencies for self-powered wearable patch device applications. This research can pave the way for a new approach to high-performance wearable and biocompatible self-sufficient electronics.

Keywords: BaTiO3 nanowires; energy harvesting; flexible; hybrid nanocomposites; piezoelectric copolymers.