Transition Metal Catalysis in the Baeyer-Villiger Oxidation of Ketones
- PMID: 29711244
- DOI: 10.1002/(SICI)1521-3773(19980518)37:9<1198::AID-ANIE1198>3.0.CO;2-Y
Transition Metal Catalysis in the Baeyer-Villiger Oxidation of Ketones
Abstract
Environmentally friendly oxidizing agents such as hydrogen peroxide or dioxygen can be used today in catalytic versions of the almost one century old Baeyer-Villiger oxidation with transition metal complexes as catalysts. On the right is a sketch of a possible mechanism for this reaction with a platinum catalyst in homogeneous solution.
Keywords: Baeyer-Villiger oxidation; Homogeneous catalysis; Ketones; Oxidations; Transition metals.
© 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.
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