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. 1998 Feb 16;37(3):323-325.
doi: 10.1002/(SICI)1521-3773(19980216)37:3<323::AID-ANIE323>3.0.CO;2-T.

New Ligands for Regio- and Enantiocontrol in Pd-Catalyzed Allylic Alkylations

Roger Prétôt  1 , Andreas Pfaltz  1
Affiliations

New Ligands for Regio- and Enantiocontrol in Pd-Catalyzed Allylic Alkylations

Roger Prétôt et al. Angew Chem Int Ed Engl. .

Abstract

The branched, chiral products 1 are formed preferentially in the allylic alkylations in Equation (1) when the Pd catalyst contains the P,N ligand L* or derivatives thereof. The ligands are readily synthesized from commercially available precursors.

Keywords: Allylic alkylations; Asymmetric catalysis; Dihydrooxazoles; N ligands; P ligands; Palladium.

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