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. 2001 Feb 2;40(3):598-600.
doi: 10.1002/1521-3773(20010202)40:3<598::AID-ANIE598>3.0.CO;2-9.

A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones

Christine G Espino  1 , J Du Bois  1
Affiliations

A Rh-Catalyzed C-H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones

Christine G Espino et al. Angew Chem Int Ed Engl. .

Abstract

Selective intramolecular alkane oxidations: an RhII carboxylate catalyzed C-H amination reaction facilitates the preparation of 1,2-amino alcohols from primary carbamates. The reaction is stereospecific, providing access to chiral α-branched amines from optically pure starting materials with no loss in enantiomeric excess.

Keywords: C−H insertion; amino alcohols; cyclization; homogeneous catalysis; rhodium.

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