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. 2001 Nov 19;40(22):4271-4274.
doi: 10.1002/1521-3773(20011119)40:22<4271::AID-ANIE4271>3.0.CO;2-H.

Assembly of Encapsulated Transition Metal Catalysts

Vincent F Slagt  1 , Joost N H Reek  1 , Paul C J Kamer  1 , Piet W N M van Leeuwen  1
Affiliations

Assembly of Encapsulated Transition Metal Catalysts

Vincent F Slagt et al. Angew Chem Int Ed Engl. .

Abstract

Enforced ligand dissociation as a result of steric interactions between ZnII porphyrin units and the N atoms of pyridylphosphane ligands determines the catalytic properties of the encapsulated transition metal complexes. These assemblies show increased catalytic activity in the palladium-catalyzed Heck reaction and rhodium-catalyzed hydroformylation. M=transition metal catalyst.

Keywords: homogeneous catalysis; porphyrinoids; self-assembly; supramolecular chemistry.

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