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. 2018 Jun 15;20(12):3566-3569.
doi: 10.1021/acs.orglett.8b01350. Epub 2018 May 25.

Total Synthesis of Originally Proposed and Revised Structure of Hetiamacin A

Gang Wu  1 , Shaowei Liu  1 , Ting Wang  1 , Zhongke Jiang  1 , Kai Lv  1 , Yucheng Wang  1 , Chenghang Sun  1
Affiliations

Total Synthesis of Originally Proposed and Revised Structure of Hetiamacin A

Gang Wu et al. Org Lett. .

Abstract

The first total synthesis of the originally proposed and correct structures of hetiamacin A has been accomplished via Wittig olefination and Sharpless asymmetric dihydroxylation reaction. These total syntheses culminated in the stereostructural confirmation of the reassignment of hetiamacin A.

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